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《Advanced Powder Technology》2022,33(6):103595
Ceria (CeO2) particles are prevalent polishing abrasive materials. Trivalent lanthanide ions are the popular category of dopants for enriched surface defects and thus improved physicochemical properties, since they are highly compatible with CeO2 lattices. Herein, a series of dendritic-like mesoporous silica (D-mSiO2)-supported samarium (Sm)-doped CeO2 nanocrystals were synthesized via a facile chemical precipitation method. The relation of the structural characteristics and chemical mechanical polishing (CMP) performances were investigated to explore the effect of Sm-doping amounts on the D-mSiO2/SmxCe1?xO2?δ (x = 0–1) composite abrasives. The involved low-modulus D-mSiO2 cores aimed to eliminate surface scratch and damage, resulting from the optimized contact behavior between abrasives and surfaces. The trivalent cerium (Ce3+) and oxygen vacancy (VO) at CeO2 surfaces were expected to be reactive sites for the material removal process over SiO2 films. The optimal oxide-CMP performances in terms of removal efficiency and surface quality were achieved by the 40% Sm-doped composite abrasives. It might be attributed to the high Ce3+ and VO concentrations and the enhancement of tribochemical reactivity between CeO2SiO2 interfaces. Furthermore, the relationship between the surface chemistry, polishing performance as well as the actual role in oxide-CMP of the D-mSiO2/SmxCe1?xO2?δ abrasives were also discussed. 相似文献
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Zhou Yu Fang Bijun Zhang Shuai Lu Xiaolong Ding Jianning 《Journal of Materials Science: Materials in Electronics》2022,33(14):10977-10989
Journal of Materials Science: Materials in Electronics - 0.95(Li0.02Na0.50K0.48)(Nb0.95Sb0.05)O3–0.05AgTaO3@BaZrO3 (LNKNbSAT@BZ) lead-free ceramics were prepared via a sol–gel... 相似文献
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《International Journal of Hydrogen Energy》2022,47(56):23787-23796
Microbial electrosynthesis (MES) is an electrochemical reduction technology through which microorganisms attached to a cathode are driven by electricity to reduce carbon dioxide (CO2) into industrial chemicals. However, the limited contact time with biocatalysts affects the performance of MES because of low CO2 solubility. In this study, zeolitic imidazolate framework-8 (ZIF-8) particles with different pore diameters modified cathodes were prepared. Results showed that the ZIF-8 modified electrode obtained the maximum acetate production rate (0.13 g L?1 d?1), which was 1.4 times that of bare CF, and the accumulated acetate concentration reached 4.04 ± 0.1 g L?1 within 30 days. Brunauer–Emmett–Teller test and CO2 adsorption characteristic evaluation indicated that ZIF-8 had a high specific surface area and an excellent CO2 adsorption capacity. Scanning electron microscopy and microbial community analysis revealed that ZIF-8 modified electrodes were beneficial to biofilm formation and increased the enrichment of Acetobacterium and Arcobacter. Therefore, CO2-adsorbing materials modified electrodes are effective in improving the performance of MES. 相似文献
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《International Journal of Hydrogen Energy》2022,47(65):28152-28164
The combustion characteristics of ammonia/methanol mixtures were investigated numerically in this study. Methanol has a dramatic promotive effect on the laminar burning velocity (LBV) of ammonia. Three mechanisms from literature and another four self-developed mechanisms constructed in this study were evaluated using the measured laminar burning velocities of ammonia/methanol mixtures from Wang et al. (Combust.Flame. 2021). Generally, none of the selected mechanisms can precisely predict the measured laminar burning velocities at all conditions. Aiming to develop a simplified and reliable mechanism for ammonia/methanol mixtures, the constructed mechanism utilized NUI Galway mechanism (Combust.Flame. 2016) as methanol sub-mechanism and the Otomo mechanism (Int. J. Hydrogen. Energy. 2018) as ammonia sub-mechanism was optimized and reduced. The reduced mechanism entitled ‘DNO-NH3’, can accurately reproduce the measured laminar burning velocities of ammonia/methanol mixtures under all conditions. A reaction path analysis of the ammonia/methanol mixtures based on the DNO-NH3 mechanism shows that methanol is not directly involved in ammonia oxidation, instead, the produced methyl radicals from methanol oxidization contribute to the dehydrogenation of ammonia. Besides, NOx emission analysis demonstrates that 60% methanol addition results in the highest NOx emissions. The most important reactions dominating the NOx consumption and production are identified in this study. 相似文献
6.
Zhai Shengnan Yu Kejing Meng Chaoran Wang Hongbo Fu Jiajia 《Journal of Materials Science》2022,57(15):7491-7502
Journal of Materials Science - In this paper, an eco-friendly method of producing hybrid silica aerogels by freeze-drying method (FD) is proposed. In the freeze-drying system, deionized water was... 相似文献
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A novel method of hydrofluidisation food freezing is numerically investigated in this paper. This technique is based on freezing small food products in a liquid medium under highly turbulent flow conditions when the heat transfer coefficient is higher than 1 000 W⋅m−2⋅K−1, which depends on the operating and flow conditions. A numerical model was developed to characterise the freezing process in terms of the heat transfer and diffusion of liquid solution components into the food product. The study investigates the freezing process of spherical samples in binary solutions of ethanol (30%) and glycerol (40%) and ternary solution of ethanol and glucose (15%/25%). The developed model was employed to determine the concentration of the liquid solution in food samples and to quantify the effect of sample size, heat transfer coefficient, solution temperature and concentration on the process. The food sample size varied from 5 to 30 mm, and the heat transfer coefficients varied from 1 000 to 4 000 W⋅ m−2⋅ K−1. The results confirm that a freezing time of 15 min for 30 mm diameter samples or less than 1 min for 5 mm diameter samples can be achieved with the hydrofluidisation method. The solution uptake was influenced by the solution type, sample size and process parameters and varied from 8.9 to 35 g of solute per kg of product for ethanol-glucose and glycerol solutions, respectively. This paper quantifies the advantages and possible limitations of hydrofluidisation, which has not yet been entirely studied, especially in terms of the mass absorption of different solutes. 相似文献
10.
《Ceramics International》2022,48(4):5091-5099
The impact of the addition of TiO2 nanoparticles and nanowires on the morphology, phase characteristics, contact angle, and electrochemical performance of chemically bonded phosphate ceramic coatings (CBPCs) was investigated. The chemical composition and surface morphology of the TiO2 nanoparticle and nanowire modified with and without (heptadecafluoro-1,1,2,2-tetradecyl) trimethoxysilane were characterized. Results indicated that the hydrophobic –CF2– and –CF3 groups were successfully introduced into the TiO2 nanoparticles and nanowires after modification. Corrosion resistance of CBPCs with TiO2 was evidently improved compared with that without TiO2. Such improvement was mainly due to the combined effects of low surface energy materials and micro/nano structures. In addition, CBPCs with TiO2 nanowires exhibited higher hydrophobicity and corrosion resistance than those with TiO2 nanoparticles because of the special columnar structure of the nanowires. 相似文献